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Ciprian Ionut Rat

Babes-Bolyai University, Cluj-Napoca, Romania

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Born: 1981

Interests: chemistry, organometallica, antimony, bismuth, X-ray, DFT, ADF, NMR

# Synthesis and characterization of organometallic compounds of low valent main group heavy elements

# Theoretical investigation of the heavy main group organometallic compounds and their complexes

Selected publications:
• Breunig, H. J.; Haddad, N.; Lork, E.; Mehring, M.; Mügge, C.; Nolde, C.; Rat, C. I.; Schürmann. Novel Sterically Congested Monoorganobismuth(III) Compounds: Synthesis, Structure, and Bismuth-Arene pi Interaction in ArBiXY (X, Y ) Br, I, OH, 2, 6-Mes2-4-t-Bu-C6H3PHO2). Organometallics, 28, p. 1202–, 2009.
• Breunig, H. J.; Bormann, T.; Lork, E.; Moldovan, O.; Rat, C. I.; Wagner, R. P. . Syntheses, crystal structures and DFT studies of [Me3EM(CO)5] (E = Sb, Bi; M = Cr, W), cis -[(Me3Sb)2Mo(CO)4], and [tBu3BiFe(CO)4]. J. Organomet. Chem. , 694, pp. 427-432, 2009.
• Breunig, H. J.; Lork, E.; Moldovan, O.; Rat, C. I. . Syntheses of a Stable Tristibine and of Related Antimony Compounds with the 2, 6-Dimesitylphenyl (Dmp) Substituent. J. Organomet. Chem. , 693, pp. 2527-2534, 2008.
• Pop, A; Rotar, A; Rat, C.; Silvestru, A. . New organophosphorus ligands with SPNSO skeleton and their copper(I) complexes: Crystal and molecular structures of (SPPh2)(O2SPh)NH, [(Ph3P)2Cu{(SPPh2)(O2SMe)N}] and [(Ph3P)2Cu{(SPPh2)(O2SC6H4Me-4)N}] & #183; 0. 5C6H5CH3. Inorg. Chim. Acta. , 361, pp. 255-261, 2007.
• Breunig, H. J.; Lork, E.; Moldovan, O, ; Rat, C. I. . 1, 1, 1, 1, 4, 4, 4, 4-Octacarbonyl-2, 2, 3, 3, 5, 5, 6, 6-octamethyl-cyclo-2, 3, 5, 6-tetraantimony-1, 4-dichromium. Acta Crystallogr., Sect. C: Cryst. Struct. Commun. , 63, pp. m548-m549, 2007.
• Breunig, H. J.; Borrmann, T.; Lork, E.; Rat, C. I.; Rosenthal, U. . Syntheses and Structures of Distibene Complexes of Tungsten and Titanium: [W(CO)5{(2, 6-Mes2C6H3)2Sb2}] (Mes = 2, 4, 6-Me3C6H2) and [Cp2Ti{(2, 6-Mes2C6H3)2Sb2)}]. Organometallics, 26, pp. 5364-5368, 2007.
• Breunig, H. J.; Lork, E.; Rat, C. I. . The complex BiCl3. CH3C6H5. Z. Naturforsch., B: Chem. Sci. , 62, pp. 1224-1226, 2007.
• Breunig, H. J.; Lork, E.; Rat, C. I.; Wagner, R. P. . Syntheses and crystal structures of [tBu3SbCr(CO)5], [tBu3BiM(CO)5] (M = Cr, W), and [tBu3BiMnCp' (CO)2] (Cp' = & #951; 5-C5H4CH3). J. Organomet. Chem. , 692, pp. 3430-3434, 2007.
• Breunig, H. J.; Borrmann, T.; Lork, E.; Rat, C. I. . Syntheses, structures and DFT study of [W(CO)5(Ph2SbX)] X = Cl, Br, I. J. Organomet. Chem. , 692, pp. 2593-2598, 2007.
• Balázs, L.; Breunig, H. J.; Lork, E.; Rat, C. I. . Syntheses and structures of stiba choline bromide, [Me3SbCH2CH2OH]Br and (Me3SbCH2COO)8(NaBr)7(MeOH)9(H2O), a supramolecular derivative of stiba betaine. Appl. Organomet. Chem. , 19, pp. 1263-1267, 2005.
• M. Szabo, M.; Ban, D.; Rat, C.; Silvestru, A.; Drake, J. E.; Hursthouse, M. B.; Light, M. E. . New versatile phosphorus ligands containing SPNSO skeleton - synthesis and characterization of (SPPh2)(O2SR)NH acids (R = Me, C6H4Me-4) and their alkali metal salts. The crystal and molecular structures of (SPPh2)(O2SR)NH. Inorg. Chim. Acta, 357, pp. 3595-3602, 2004.


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