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Marilena Ferbinteanu Cimpoesu

University of Bucharest, Faculty of Chemistry, Inorganic Chemistry Department, Bucharest, Romania

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Born: 1968

Interests: Coordination Chemistry, Magnetism, Chromotropism, Stereochemistry, Structural Chemistry, Clusters

Post-Doc. (2005-2006) Japan Society for Promotion Science Fellowship;–research stage at Tohoku University, Sendai, Japan (Prof. Masahiro Yamashita); Topic of the Project: Design and Advanced Studies of New Single Chain Magnets.

Post-Doc. (2003-2004)–research stage at Tokyo Metropolitan University, Tokyo, Japan (Prof. Masahiro Yamashita); Topic of the Research: Single Chain Magnet (CREST project).

Post-Doc. (2002-2003)–research stage at Ochanomizu University, Tokyo, Japan
(Prof. Yutaka Fukuda); Topic of theResearch: The Chemistry of the Thermochromic and Solvatochromic Coordination Compounds. New Classes, Synthetic Strategies and Advanced Structural Investigations.

Post-Doc. (1999-2001) “Alexander von Humboldt” Fellowship –research stage at Institut für Anorganische Chemie der Universität Göttingen
(Prof. Herbert W. Roesky); Topic of the Project: Hard and Soft Interactions for generating new catalysts.

Ph.D. (1998) University of Bucharest; Faculty of Chemistry, (Prof. M. Brezeanu); Topic of Thesis: Coordination Compound Displaying Thermochromic Properties.

M.S.(1991) University of Bucharest, specialization Inorganic Chemistry

Current research topics: The mechanics of the ferromagnetic coupling in a Mn(III)-Mn(III)-Fe(III) single chain magnet; Spin coupling between M ions through cyanide, radicals, carboxylates as bridging ligands and spin coupling in supramolecular structures; Ligand Field Driven Magnetic Anisotropy in new Mn(III) complexes; Tuning the single molecule magnet behavior in d-f heterometallic complexes; Symmetry mechanism insight in the luminescent properties of lanthanide clusters.

Research methodology: My work envisaged interdisciplinary goals and procedures, including synthesis, characterization by modern measurements and interpretation by advanced and new models of the important features related with exchange coupling, magnetic anisotropy and mechanisms of slow relaxation of magnetization, whose interplay are determining interesting magnetic properties. The work placed on equal footing the experimental part and the advanced interpretation and modeling.

Selected publications:
• S. Wang, M. Ferbinteanu, M. Yamashita. Cyanide-Bridged Fe(III)-Mn(III) Chain with Metamagnetic Properties and. Inorganic Chemistry, 46, pp. 610-612, 2007.
• L. Maretti, M. Ferbinteanu, F. Cimpoesu, S, S. M. Islam, Y. Ohba, T. Kajiwara, M. Yamashita, S. Yamauchi. Spin Coupling in the Supramolecular Structure of a New Tetra(QuinolineTEMPO)Yttrium(III)Complex. Inorganic Chemistry, 46, pp. 660-669, 2007.
• T. Kajiwara, K. Katagiri, M. Hasegawa, A. Ishii, M. Ferbinteanu, S. Takaishi, T. Ito, M. Yamashita, N. Iki. Conformation-Controlled Luminescent Properties of Lanthanide Clusters Containing p-tert-Butyl sulfonylcalix[4]arene. INORGANIC CHEMISTRY, 45, pp. 4880-4882, 2006.
• M. Ferbinteanu, T. Kajiwara, K-Y Choi, H. Nojiri, A. Nakamoto, N. Kojima, F. Cimpoesu, Y. Fujimura, S. Takaishi, M. Yamashita. A Binuclear Fe(III)Dy(III) Single Molecule Magnet. Quantum Effects and Models. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 128, pp. 9008-90009, 2006.
• Cimpoesu, F, Hirao, K, Ferbinteanu, M, Fukuda, Y, Linert, W, . New keys for old keywords. Case studies within the updated paradigms of the hybridization and aromaticity. MONATSHEFTE FUR CHEMIE, , 136 (6), pp. 1071-1085, 2005.
• M. Ferbinteanu, H. Miyasaka, W. Wernsdorfer, K. Nakata, K. Sugiura, M. Yamashita, C. Coulon, and R. Clerac. Single-Chain Magnet (NEt4)[Mn2(5-MeOsalen)2Fe(CN)6] Made of MnIII-FeIII-MnIII Trinuclear Single-Molecule Magnet with an ST= 9/2 Spin Ground State. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 127, pp. 3090-3099, 2005.
• J. Paulovic, F. Cimpoesu, M. Ferbinteanu, K. Hirao. Mechanism of Ferromagnetic Coupling in Copper(II)-Gadolinium(III) Complexes. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 126, pp. 3321-3331, 2004.
• Mosch-Zanetti, NC, Ferbinteanu, M, Magull, J. A new mu(4)-oxo tetranuclear magnesium compound: Coordination effects of the azolato ligands. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, (4), pp. 950-956, 2002.
• Hatop, H, Ferbinteanu, M, Roesky, HW, Cimpoesu, F, Schiefer, M, Schmidt, HG, Noltemeyer, M. Lightest member of the basic carboxylate structural pattern: [Al-3(mu(3)-O)(mu-O2CCF3)(6)(THF)(3)][(Me3Si)(3)CAl(O2CCF3)(3)]center dot C7H8. INORGANIC CHEMISTRY, 41 (4), pp. 1022-+, 2002.
• Stasch, A, Ferbinteanu, M, Prust, J, Zheng, WJ, Cimpoesu, F, Roesky, HW, Magull, J, Schmidt, HG, Noltemeyer, M, . Syntheses, structures, and surface aromaticity of the new carbaalane [(AlH)(6)(AlNMe3)(2)(CCH2R)(6)] (R = Ph, CH2SiMe3) and a stepwise functionalization of the inner and outer sphere of the cluster. . JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 124 (19), pp. 5441-5448, 2002.
• Ferbinteanu, M, Roesky, HW, Cimpoesu, F, Atanasov, M, Kopke, S, Herbst-Irmer, R. New synthetic and structural aspects in the chemistry of alkylaluminum fluorides. The mutual influence of hard and soft ligands and the hybridization as rigorous structural criterion. INORGANIC CHEMISTRY, 40 (19), pp. 4947-4955, 2001.


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