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Sergiu Coseri and Keith Ingold. Distinguishing between Abstraction and addition as the First step in the Reaction of a Nitroxyl Radical with Cyclohexene. Organic Letters, 6 (10), pp. 1641-1643, 2004.

Abstract: An unambiguous method for distinguishing between abstraction-addition and addition-abstraction mechanisms (and mixtures thereof) in the reaction of 4-hydroxy-2,2,6,6-tetramethylpiperidine-N-oxyl with a specifically deuterated cyclohexene, 1,2-dideuterocyclohexene, is demonstrated

Keywords: cyclohexene reactions, radicals, reaction mechahism

Posted by Sergiu Coseri

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